I recently had the problem that my VLC Media Player took about a minute to start. First I didn’t know what caused the problem until I remembered that I imported my Music Library into VLC, so it always scanned the whole Library to import the meta data.
To disable the Media Library do as follows:
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Open: Tools -> Preferences
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Under Show Setting select “All” to show all settings
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Go to: Playlist
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Uncheck “Use Media Library”
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Click “Save” to finish
Now your VLC should start up quickly again.